|
 
- UID
- 14639
- 帖子
- 631
- 积分
- 5413
- 威望
- 431 点
- 金钱
- 1042 分析元
- 贡献
- 2028 分
- 文采
- 1531 分
- 阅读权限
- 150
- 注册时间
- 2007-3-29
|
分析化学相关词汇英语翻译
您可以下下来、慢慢细细“品尝”8 y- \4 T* l w' g
8 F: j( Y- y3 [* l0 Z; D3 ]1 z2 _5 N( v8 J+ r# O
) [3 J2 l7 b+ P! [$ A& }- D玻璃漏斗 Glass funnel long stem, r$ g9 [ A/ H" ]" O) p
试管 test tube test tube brush test tube holder test tube rack
6 X: ^. y! Y) h蒸发皿 evaporating dish small+ k+ ~, K. ~+ Z, D6 J
烧杯 beaker' w: b* o' l! d) S
锥形瓶 Erlenmeyer, L6 y u$ l# f) n
量筒 grad cylinder. ]% W9 X% d2 @; j; [- V
洗瓶 plastic wash bottle* T/ X/ [5 s; j- d( i2 }/ N! m& q! J
勺皿 casserole ,small
C8 s+ ~" Y' g4 G" cstoppered flask7 G1 \4 z) d8 j6 M$ y! H
分液漏斗 separalory funnel
* `: o5 Z, G; Q) E0 {9 T* i8 H) Ewater bath/oil bath8 [% U) n- _8 i7 A7 S W) s' {/ e/ y' q
strring bar' S, f5 A9 {! t0 i9 s# X
magnetic stirrer; o n' n6 \+ s% z2 e% V
冷凝器 condenser* V! F1 H5 G: n. s
Ballast bottle5 K2 ~9 p" [4 m) z
圆颈烧瓶 Round-buttom flask
7 x# U8 l5 d0 N: V1 z试剂瓶 reagent bottles
% \) P/ N4 A; i6 n) |, n$ J托盘天平 platform balance 台秤9 x" f Q; P, [6 x0 H5 z6 N
0.1g 托盘pan 指针刻度表pointer and scale
% h- a% `8 R1 A; c6 ^crossbeams and sliding weights 游码
: I ?$ F& y5 {分析天平 two-pan/single-pan analytical balance' D; Z8 Z- b! W' W/ k5 y
滴定管 burette glass bead(basic) nozzle
( `6 c! J7 N. |4 j& ]移液管 pipette 胖肚 elongated glass bulb5 z: K! ^! G- |) G" N. s; x0 a2 V
洗耳球 rubber suction bulb
- b" e1 B0 ]3 X4 V$ p0 m玻棒 glass rod
) \2 h9 G* I/ g2 A3 D& B( P: e0 V玻璃活塞 stopcock8 d- A* E' T& s% G1 u
容量瓶 pyknowmeter flasks" @) ^) h8 Z& ]! w
比重瓶 (one-mark)volumetric flasks
: m0 m2 Y S) |! g/ _6 h9 O/ X胖肚吸管 one-mark pipette
3 U; x) ], m# u- ~( g$ }: d刻度吸管 graduated pipettes
5 f+ I2 u7 N5 D6 n7 Y. ?0 N实验仪器清单
! z1 y6 C' d# U1 c1、 柜子中 四、抽屉中:
2 }5 ^) m: `0 I6 P0 H- S锥形瓶(conical flask) 250ml×4 药匙(medicine spoon)×1! i+ @* [$ z8 L3 N" O/ m
(Erlenmeyer flask) 100 ml×3 滴管(drip tube;dropper)×26 j" l# R# M3 I3 {
烧杯(beaker) 500 ml×1 玻棒(Glass stic)×2
3 X1 `9 U. D' \0 \5 X) C250 ml×3 木试管夹(test tube clamp;test tube holder)×1
6 \2 _) e7 s0 w5 E( B) b100 ml×3 胖肚吸管(straws) 25 ml×1% z* D' S- j" q! L2 u2 c0 h
50 ml×2 10 ml×1
. \0 P! i- T. u/ A, ]容量瓶(volumetric flask) 100 ml×2 乳钵(morta)×10 L; m* q" P: S Z) f v4 N
50 ml×4 洗耳球(ear wadhing bulb)
- I ~/ P3 d, i/ E; o9 j4 ?# h- u碘量瓶 (iodin numoe flask;iodineflask) 500 ml×3% o+ ?2 z6 b* B, L9 i+ c, `6 Y4 ], b
试剂瓶 (reagent bottle) (无色)×28 O$ F. }" `* k' f6 t/ l* h
(棕色)×2 配洗液:/ E N8 o, c. K9 p, L0 j% U
量筒(cylinder) 100 ml×1 K2Cr2O72g+5ml水→65mlH2SO4
7 O7 X, y" R! e3 c( `(graduated cylinder)10ml×1 边加边搅拌(stir)。
( |8 d3 i* w* O, r8 }7 y Q二、台面上仪器: 一般仪器的洗涤(wash)% U( H5 @9 C' O; Z9 X* T0 L# p
铁支架(siderocradle)+蝴蝶架
$ a m4 X. l9 J% {( Z2 P) d$ E. E白瓷板(White Porcelain Board ) (一)清点仪器(to count;to make an inventory)
- {. d& W1 Q! n# g2 [% {2 Y+ a酸式滴定管(Acid burette) 25 ml×1 配洗液 (Lotion)
. ^. M$ ]3 \# J' ^2 f: _1 Q2 ?碱式滴定管(Alkali burette)25 ml×1 一般仪器的洗涤( y3 S' z1 J3 Q" S$ [" ]: P: e* n
三、公用柜中: (二)滴定管(buret;burette)7 y# l' ~# Q# _% y* P; W- a, x# H
直型冷凝器(rectocondensor)×1 容量瓶(volumetric flask)8 }: j% s; C5 f
漏斗架 (funnel stand) ×2 移液管(pipe)8 X, j$ d* d% [6 A- H9 J! J
水浴锅(water bath kettle) ×13 z3 b1 Y' e( A- }- v
温度计(Thermometer;hygrometer;hydroscope) ×1
" ~9 k2 s1 ~( c+ D电炉(electric furnace;electric hot plate;electric stove) 四人一个
: e+ w; I$ w2 S9 P! y* h+ d* m《分析化学》上册+ }+ K0 ^- m8 H- {( A$ H! g! s% d
第一章 绪论" M b& N! f$ ?
分析化学:analytical chemistry1 E# l `* G' F% m$ n
定性分析:qualitative analysis
; {9 q( B8 S) S% z- U g- b定量分析:quantitative analysis
* p5 Z3 c0 N4 b% @# z9 ` D5 |, r物理分析:physical analysis
4 L- M2 N: B* R& [* R物理化学分析:physico-chemical analysis
" E- t1 T. Y$ T) P g9 }5 `5 `/ C仪器分析法:instrumental analysis
3 X, ?. Y" A1 a流动注射分析法:flow injection analysis;FIA1 E( |3 C5 n$ |: R# H
顺序注射分析法:sequentical injection analysis;SIA
+ P& @0 w) |8 G7 y化学计量学:chemometrics
$ [% Y1 K% E( z7 M, X9 k第二章 误差的分析数据处理
$ j0 T# a& y( z1 ?! c+ C1 X0 @. _绝对误差:absolute error2 E, g }1 G* J' b
相对误差:relative error
: Y b9 ?! m, Y- _7 u" G系统误差:systematic error
, T2 e" l" u- J3 s% H; i7 C' D" E可定误差:determinate error% |5 h4 V$ o X0 h4 u8 h
随机误差:accidental error
v/ J9 ]9 ^ J! O不可定误差:indeterminate error
" g/ D5 }; @ d准确度:accuracy5 x. B/ q3 k' a. n
精确度:precision2 _( t6 z( D) k/ I6 Y0 ?# t
偏差:debiation,d
- S, |( C9 l R5 N: S平均偏差:average debiation' O" L3 i0 {$ @8 ^
相对平均偏差:relative average debiation
, v) R# @) f2 J5 D1 E标准偏差(标准差):standerd deviation;S
}5 q, R) O1 P% b, U( j相对平均偏差:relatibe standard deviation;RSD
3 a0 @* W" s! U z变异系数:coefficient of variation( J0 `$ d1 Q5 M) |0 j
误差传递:propagation of error
0 x' ~$ K* o1 T# \- ^5 b有效数字:significant figure. M& O# e+ q" W9 a
置信水平:confidence level
' s0 ~) A/ h! A$ s2 T显著性水平:level of significance
i' I3 R# k% K合并标准偏差(组合标准差):pooled standard debiation9 P# F4 }- n7 G, Z# ^* M
舍弃商:rejection quotient ;Q
, q( K# @9 N" z* w# W2 c6 F9 }化学定量分析9 m- f; F6 D! x }
第三章 滴定分析概论' p- f# X0 c' {; z2 |! l
滴定分析法:titrametric analysis& `; k3 y( E' A! ?# g r
滴定:titration
; K {! Q" u3 C8 G6 `7 _容量分析法:volumetric analysis2 r8 d) u8 U* t, q& Z- W o
化学计量点:stoichiometric point
/ d+ S. o2 j5 ~0 }1 x' l$ f等当点:equivalent point! w8 v R& _. e
电荷平衡:charge balance+ ]# o/ M$ b$ w$ g) V
电荷平衡式:charge balance equation4 W3 Q7 T# t' d' g
质量平衡:mass balance5 [8 @ M5 l3 ]( C: C& E
物料平衡:material balance! o" D! H$ I* o' d: h) D% T
质量平衡式:mass balance equation
* j' @) h0 d- G6 }5 E9 S第四章 酸碱滴定法
( u* e: [: I, U酸碱滴定法:acid-base titrations1 c# r& y! Z$ h. j9 x. K! B! [
质子自递反应:autoprotolysis reaction+ L' G# R! V5 t' I; s+ G
质子自递常数:autoprotolysis constant
2 o$ X; G) r' r; k质子条件式:proton balance equation
7 I. i/ N, x/ u. d7 c酸碱指示剂:acid-base indicator1 N4 }5 U7 ]. M, m
指示剂常数:indicator constant
( C. Z$ M) H9 M& n! y变色范围:colour change interval' s; s/ f8 Q' f( a0 `
混合指示剂:mixed indicator! ~/ t* @/ P. Z! q$ L& [( O
双指示剂滴定法:double indicator titration- v/ M4 D; k# u; d, t
第五章 非水滴定法
7 T+ R3 n' r# A+ _" V2 H7 R非水滴定法:nonaqueous titrations
; W c! r1 X5 R& I5 ]! p8 j7 e+ J质子溶剂:protonic solvent
6 P: C+ D4 {6 M$ [ h, D酸性溶剂:acid solvent% o' n& s. j0 q( C, X$ b' [' ]! W
碱性溶剂:basic solvent6 y3 ~5 _# |# a; l8 ~3 f# T
两性溶剂:amphototeric solvent
0 N. K; S* s' _+ q6 Q: \7 a: S无质子溶剂:aprotic solvent" u7 m: W5 ~7 i4 x9 t
均化效应:differentiating effect# z' i7 z; Z+ K3 Z: ? U
区分性溶剂:differentiating solvent- x: W2 k* O, D, ^7 z$ k
离子化:ionization
7 T9 {: ^2 _8 [9 d6 p8 \0 P; x w离解:dissociation: ^+ ] |0 n) I5 {: T7 W2 J
结晶紫:crystal violet( O: Q; a; J, [( x% ]4 M
萘酚苯甲醇: α-naphthalphenol benzyl alcohol# q6 S; O' ~! F
奎哪啶红:quinadinered8 @6 O5 s7 h5 K+ R
百里酚蓝:thymol blue
+ ~$ b$ h6 E" x1 K/ U5 w偶氮紫:azo violet
q4 i. j, j/ p) q- Z溴酚蓝:bromophenol blue
: E2 G' |8 c) D0 p& {第六章 配位滴定法
% ?' _6 `5 a* d* \配位滴定法:compleximetry
( c7 M; I1 y7 V9 _乙二胺四乙酸:ethylenediamine tetraacetic acid,EDTA5 R2 j, v9 T1 `4 Z) a3 R
螯合物:chelate compound
" ?# B6 F( |4 O! f1 x: ?, G( [: t; I金属指示剂:metal lochrome indcator
6 T# v. m7 Q) ^第七章 氧化还原滴定法* k" g/ v. b( J* o
氧化还原滴定法:oxidation-reduction titration
1 S, r* W i2 Y/ v碘量法:iodimetry# J' C' o+ i1 Y, q
溴量法:bromimetry ]
0 T( k8 Q, ^# G1 r溴量法:bromine method" E1 D7 F& G4 P5 y u$ B% j, M
铈量法:cerimetry
, e( i; G" j/ `! v; r高锰酸钾法:potassium permanganate method; Z+ [) J& L, S, N+ |
条件电位:conditional potential
' k% Y: j9 M3 r' I溴酸钾法:potassium bromate method4 C! \$ }+ e8 O; ~8 K
硫酸铈法:cerium sulphate method
0 u& u4 Q5 O9 J+ H; U* b+ T偏高碘酸:metaperiodic acid
* ?- O! Q1 R5 G8 ^5 q- N高碘酸盐:periodate
! E) z+ o! T9 K9 {8 c# x亚硝酸钠法:sodium nitrite method1 f n/ ]- R- e) ?' j( M
重氮化反应:diazotization reaction
1 N e1 X: J* B6 Y重氮化滴定法:diazotization titration B: N% J' u1 G
亚硝基化反应:nitrozation reaction8 W4 p! j! _6 J9 |
亚硝基化滴定法:nitrozation titration( u0 N& U: j* t5 p
外指示剂:external indicator4 {5 E8 l1 \- t4 e
外指示剂:outside indicator
. _3 E3 \& I) A& ^- q" v8 S重铬酸钾法:potassium dichromate method3 g* y9 o% t/ a c0 ]* g2 n8 j
第八章 沉淀滴定法
( f* G8 R2 C1 d; H8 z. e" P沉淀滴定法:precipitation titration
6 [) z; H5 H' D$ C容量滴定法:volumetric precipitation method
$ c. v. e! f; C w) U& K, }0 x9 `银量法:argentometric method( s3 S u3 i* w5 X/ r
第九章 重量分析法
5 y( J7 e. {( @重量分析法:gravimetric analysis6 q# x5 e2 E- B6 ]( B+ B
挥发法:volatilization method" A; G5 Y4 M( X9 v4 i
引湿水(湿存水):water of hydroscopicity
5 l( H' R2 ^5 X包埋(藏)水:occluded water
7 u+ ?5 z# M/ j) w. f1 L吸入水:water of imbibition
6 s/ `/ h! c! m# J结晶水:water of crystallization
+ l5 h) [$ A; ~% C+ }# K1 r+ E组成水:water of composition7 c9 x2 _+ M- J+ X+ g2 ^+ c; K$ I/ O
液-液萃取法:liquid-liquid extration1 @# u0 q4 w6 E3 k
溶剂萃取法:solvent extration. H+ } ^0 q: P" M
反萃取:counter extraction6 Q+ X% m1 \$ ~* a. f8 D) ?4 D% i
分配系数:partition coefficient6 w4 h: G( q# F K8 ~* P
分配比:distribution ratio4 M8 y- f+ c0 u C7 q
离子对(离子缔合物):ion pair
3 U2 o8 ? v- f- Q1 S. ^) V沉淀形式:precipitation forms% K9 a0 r4 T# }& \
称量形式:weighing forms9 \: X$ w+ R( R! l( s* B
《分析化学》下册
. g) }. Q- \! `$ W+ M8 p) a$ C7 _7 Q3 j仪器分析 概述
/ R* ]' ?. L/ D1 B) j& E3 @物理分析:physical analysis; }( l' F5 E! V7 J9 `* u
物理化学分析:physicochemical analysis
# J8 [4 t, M/ i! e7 }4 n* g8 n% c" p仪器分析:instrumental analysis, `% |, R3 @4 E" N1 K) v
第十章 电位法及永停滴定法- b. t/ h$ B5 t
电化学分析:electrochemical analysis" U4 g4 c. Q/ ~9 j1 z+ Z
电解法:electrolytic analysis method1 i* w9 o% V4 }- L: o: U. D
电重量法:electtogravimetry, M8 j S6 N' }; O3 _
库仑法:coulometry
! c3 _0 E& T$ q# R库仑滴定法:coulometric titration! g0 I/ s5 Z h5 S. [! b- E
电导法:conductometry1 Z" I8 m3 h0 _3 D6 ]* v6 w
电导分析法:conductometric analysis
) Z. n/ M8 K9 O, a9 q/ l" B) m电导滴定法:conductometric titration# p! f4 K% v" D5 U8 Z" u
电位法:potentiometry6 n! X/ B" D2 v* B- `
直接电位法:dirext potentiometry) r7 O6 g* N- U7 Z
电位滴定法:potentiometric titration
5 H' ^: N3 d% a) q- B5 W/ ]伏安法:voltammetry
" K7 T: V& \: b# n& m$ B; b极谱法:polarography8 P' |/ d, e; U; b6 z4 Y4 v
溶出法:stripping method
2 A l. h$ `* U) E) W电流滴定法:amperometric titration3 A% F9 F2 t$ m9 d9 v8 S W
化学双电层:chemical double layer
4 |- b7 v4 } I8 T相界电位:phase boundary potential
$ W9 O$ \* Q) |8 p1 b# @( |* D& F5 b( ~金属电极电位:electrode potential* X F6 Z0 L/ t9 s, V9 ~
化学电池:chemical cell% B7 u7 a+ M$ T' _+ E/ {: K9 ^& _
液接界面:liquid junction boundary
) ?4 J% F, X! r# E+ ?3 s6 y原电池:galvanic cell
/ J& { F" D! @! Y2 Q; }9 w# k8 ?5 K电解池:electrolytic cell
( D6 j( L# o4 Y D+ D负极:cathrode, r/ ?$ Y n. W$ d* [/ `. A! a& [4 ~
正极:anode
7 i: G `! K* x6 D电池电动势:eletromotive force
2 P, i. b0 c: t' d8 t Q% {指示电极:indicator electrode
. h# {* b+ Z8 l" t参比电极:reference electroade
+ ?. c0 h3 j+ C7 b( o1 c1 [7 K标准氢电极:standard hydrogen electrode8 f: D5 U/ C* H. G9 ^
一级参比电极:primary reference electrode
/ Q v8 d$ n; }" W% n' e! x) b" U饱和甘汞电极:standard calomel electrode
( x, x! } w2 ~# S$ n+ Y银-氯化银电极:silver silver-chloride electrode
! t4 z# }# |+ S, P3 Q4 B液接界面:liquid junction boundary5 Q3 Y. m7 t$ s& w; n3 @# W
不对称电位:asymmetry potential: r0 N# b8 {+ v
表观PH值:apparent PH, Z% @( `+ ]/ o1 f9 B% w1 F9 @
复合PH电极:combination PH electrode; ]7 g( R* Q/ k+ _: j) \2 W. ?
离子选择电极:ion selective electrode
$ m* c1 x$ K( j# ?4 W/ Z9 M! A; l敏感器:sensor a( ?8 |: I/ M$ z, q
晶体电极:crystalline electrodes5 c' `* q* C3 S; d- d
均相膜电极:homogeneous membrance electrodes
+ z# M' t' v Q4 R; @非均相膜电极:heterog eneous membrance electrodes* x9 e: A* |5 V, N2 l2 z1 x
非晶体电极:non- crystalline electrodes9 n3 I8 R2 ^% |
刚性基质电极:rigid matrix electrode h* Q( l7 s3 t/ P' j
流流体载动电极:electrode with a mobile carrier% w) G; e. p* M( ?) N( q7 `
气敏电极:gas sensing electrodes+ X* b: C- L3 ?2 t% d) Q3 H
酶电极:enzyme electrodes! r& o( o& p- I
金属氧化物半导体场效应晶体管:MOSFET
9 B9 K% Z! X/ W8 _- W6 ^离子选择场效应管:ISFET
) ` a0 u+ q( B2 ^4 i, {总离子强度调节缓冲剂:total ion strength adjustment buffer,TISAB
$ x$ o* I8 S1 C6 [+ O永停滴定法:dead-stop titration4 v& d7 ]8 d9 Q+ I- P
双电流滴定法(双安培滴定法):double amperometric titration
8 [5 w1 P( L( _" ]4 d第十一章 光谱分析法概论, P g2 I% u* q
普朗克常数:Plank constant
8 b4 c$ [# s7 w+ E3 H0 h& |. S$ Y电磁波谱:electromagnetic spectrum& f$ q% j* U+ Y: R% P! d
光谱:spectrum2 n7 l* a1 b6 p
光谱分析法:spectroscopic analysis8 G V1 U6 d$ C" S$ Q
原子发射光谱法:atomic emission spectroscopy; [5 |: u0 A. }5 S$ v$ L5 t
质量谱:mass spectrum
1 U1 g( W, @- w! I, ?' M+ Q: g* Z7 V `质谱法:mass spectroscopy,MS
: C" Q! Z0 Z" E d第十二章 紫外-可见分光光度法
9 C6 V9 L6 Q4 `5 D* d0 U紫外-可见分光光度法:ultraviolet and visible spectrophotometry;UV-vis: q/ x5 p; P J% h1 d
肩峰:shoulder peak
* k( P! J! j1 Z( [末端吸收:end absorbtion
! O6 X2 z+ e. y& U2 l8 H. S6 Y生色团:chromophore
& Z: S/ k( ]( V J# U. f0 _助色团:auxochrome
8 K5 A! N7 T7 K红移:red shift
$ X0 C4 v! b3 |" b/ j长移:bathochromic shift9 O: F `" Q- m6 W: M' [6 J# {5 J
短移:hypsochromic shift) ]* A" }4 |+ ]* l
蓝(紫)移:blue shift
" j0 {1 p1 s9 X4 ~* c增色效应(浓色效应):hyperchromic effect, G0 I* [# j$ Z O5 A3 H
减色效应(淡色效应):hypochromic effect
& e+ s( G+ {0 P/ v6 R5 v强带:strong band
5 C1 g! E. f$ E弱带:weak band
! Q" }2 b' W# @! L6 k6 [( ~吸收带:absorption band4 Q% q# }5 S6 ^ L9 ]1 _
透光率:transmitance,T
+ o. X0 z$ [5 Z6 s吸光度:absorbance, {% ], F# r" j0 T9 E, W8 g% c
谱带宽度:band width
, B3 S4 ~2 H/ p8 @. `" G杂散光:stray light. L/ O5 Z2 V7 t9 E+ D
噪声:noise
3 \7 D8 V- D& Q8 L0 b7 F暗噪声:dark noise
4 O0 `. ]( W- m" u散粒噪声:signal shot noise
( _9 ^2 W) U0 }% A闪耀光栅:blazed grating
( R: V Z2 o; g全息光栅:holographic graaing
2 i4 @# V6 l* V% v9 a% N- b+ i光二极管阵列检测器:photodiode array detector
6 D Z5 O; `8 n+ K: c" N偏最小二乘法:partial least squares method ,PLS
4 B+ ^, ]0 m# v& S6 l2 q4 R褶合光谱法:convolution spectrometry9 f6 l/ D1 ~# n# C1 \
褶合变换:convolution transform,CT
) E. e8 ~9 f0 L离散小波变换:wavelet transform,WT
& Y6 _1 H C$ r/ x5 k# }多尺度细化分析:multiscale analysis* O8 K, r7 v- q1 m/ Y0 G
供电子取代基:electron donating group
i, o8 w8 e- n吸电子取代基:electron with-drawing group
# B |! o; O8 w6 G4 N: A, M第十三章 荧光分析法
1 G5 h. u" h1 H M+ x荧光:fluorescence
( n3 C+ F; {5 E) y荧光分析法:fluorometry' f* Z9 n3 b* M
X-射线荧光分析法:X-ray fulorometry
0 ^! c( g4 Z3 x' S原子荧光分析法:atomic fluorometry8 o% G/ c0 Z8 L2 B
分子荧光分析法:molecular fluorometry
/ q4 \- ]1 \6 a V" `' O振动弛豫:vibrational relexation
9 d/ |9 W1 a. w! y m" n; w内转换:internal conversion( q0 j, z* s: ?# X, P
外转换:external conversion, m* s( E9 P6 h2 r
体系间跨越:intersystem crossing
/ t- s) H. J0 s0 U) j, C" h$ E激发光谱:excitation spectrum2 Q5 q" H( C" B+ Y P, R- d6 M2 t
荧光光谱:fluorescence spectrum
1 Y; \$ b% n7 } i( v斯托克斯位移:Stokes shift' A7 P) i6 T, E
荧光寿命:fluorescence life time
) H7 Q7 Y- ~( E `; h/ S* Q荧光效率:fluorescence efficiency
2 U: Z u1 Z8 L2 X* N) ^2 Z4 D荧光量子产率:fluorescence quantum yield
, y6 |/ D2 {; t! r" o荧光熄灭法:fluorescence quemching method, Q0 x8 Z! O8 V! x$ d% j
散射光:scattering light6 O% E! |9 [/ v) P: j
瑞利光:Reyleith scanttering light
, k) N. b+ e. b拉曼光:Raman scattering light
8 Q5 I, T) p9 T3 R第十四章 红外分光光度法
5 ^( l6 ^- k" N, K1 M2 G红外线:infrared ray,IR
2 E t2 Z4 N6 a$ P3 f X# V ]1 I中红外吸收光谱:mid-infrared absorption spectrum,Mid-IR
) U; W- H& C4 J5 n远红外光谱:Far-IR
3 {& m6 m% ]5 _* D2 e微波谱:microwave spectrum,MV
' y/ U B! v" W/ r红外吸收光谱法:infrared spectroscopy2 Z) r& ~) s0 K+ u# N" M
红外分光光度法:infrared spectrophotometry
) f/ L, l6 J/ m4 u, a3 n' e振动形式:mode of vibration; i0 B' j3 y2 ], w& E. H9 E6 d9 H
伸缩振动:stretching vibration
: [/ s% N& y4 i; s7 m# {对称伸缩振动:symmetrical stretching vibration
0 Y9 g( q/ J- O$ Q# s5 n5 f1 G不对称伸缩振动:asymmetrical stretching vibration
+ T0 ~" ?/ Q( @! k弯曲振动:bending vibration% h( S# c: b, n
变形振动:formation vibration- t' t! L2 F- F+ i7 }
面内弯曲振动:in-plane bending vibration,β9 Z$ w1 @2 h: C( |. p7 M
剪式振动:scissoring vibration,δ
4 ~, t4 _& A4 h& b面内摇摆振动:rocking vibration,ρ5 M% |! e! z! D9 m& W7 R
面外弯曲振动:out-of-plane bending vibration,γ d' i+ s) [3 H- |9 ]$ @
面外摇摆振动:wagging vibration,ω+ D( s* C) u, A+ C: Q7 Z! V% s/ y
蜷曲振动:twisting vibration ,τ' L; Q" Z% j+ Z2 Y- b2 \, M* r! u
对称变形振动:symmetrical deformation vibration ,δs
* |0 k" x/ p, F7 _不对称变形振动:asymmetrical deformation vibration, δas
7 R a3 P `* L0 \' ]# N9 Z7 I/ A* l6 s特征吸收峰:charateristic avsorption band
6 A& `2 W/ n" ^( [% X6 u特征频率:characteristic frequency
/ I1 l# {' Q% T0 r e/ J3 j/ m0 x$ ^相关吸收峰:correlation absorption band
( M( J0 s8 o! h/ K& h6 O3 O杂化影响:hybridization affect$ F# p0 G( |" M+ i a
环大小效应:ring size effect
% [$ l* q3 I! C( _# ^% U吸收峰的强度:intensity of absorption band
( B) |5 ?; l: J环折叠振动:ring prckering vibration
b/ c, N. t- H% ]+ o3 m2 m第十五章 原子吸收分光光度法
. O( r, G: ~' |0 S3 g3 a9 P8 T原子光谱法:atomic spectroscopy; `+ P* Z3 K* \/ I' f+ X
原子吸收分光光度法:atomic absorption spectrophotometry,AAS. S# r, x/ {* O2 c! L# r) K' v! S
原子发射分光光度法:atomic emmsion spectrophotometry,AES4 w9 D5 G; L# [: G3 h7 G" S
原子荧光分光光度法:atomic fluorescence spectrophotometry,AFS
! c: W0 }3 ~+ O第十六章 核磁共振波谱法 P$ g/ W# Z7 x& A, g U3 A+ T
核磁共振:nuclear magnetic resonance,NMR( x# v' \! Z" R9 ~ @& S6 D: h0 p
核磁共振波谱:NMR spectrum+ `8 A- k# G+ u6 L% d
核磁共振波谱法:NMR spectroscopy
" J1 G2 c, c) }扫场:swept field- L9 K* C1 _" A% G
扫频:seept frequency% @6 i: b# k/ X( K
连续波核磁共振:continuous wave NMR,CW NMR4 r0 H4 [, {, {' F7 H8 q
Fourier变换NMR:PFT-NMR,FT-NMR8 _3 |3 {& K! f; q$ b% r, y
二维核磁共振谱:2D-NMR* q0 c1 O( a) C$ K
质子核磁共振谱:proton magnetic resonance spectrum,PMR3 \) }. N8 |3 z7 e) }1 C
氢谱:1H-NMR
: ]) }% d4 Y" Z4 V* D0 T碳-13核磁共振谱:13C-NMR spectrum,13CNMR
/ ^0 z4 W) _4 ?0 y7 j- W自旋角动量:spin angular momentum
* k% u7 y% l/ m% P8 c磁旋比:magnetogyric ratio
" a$ m% i7 Q# H7 r- c: _/ @ Q磁量子数:magnetic quantum number,m( T0 ^" }% O, z4 N4 K' T
进动:precession' { j! F9 V3 _3 F. I
弛豫历程:relaxation mechanism
+ \* g* m( [* f. Y5 F局部抗磁屏蔽:local diamagnetic shielding
: s' ]4 f0 C9 N, m- D屏蔽常数:shielding constant- y N, L* G# B& d
化学位移:chemical shift0 j5 F1 |( [6 \$ o. F
国际纯粹与应用化学协会:IUPAC
C0 Q9 M3 e4 `' }$ J5 k磁各向异性:magnetic anisotropy
# d: [' }& B, z* |/ M- J8 Z, k远程屏蔽效应:long range shielding effect
, d! ^* Z1 h/ s+ z结面:nodal plane9 S8 ^2 _& l3 s& G1 y" r8 t
自旋-自旋偶合:spin-spin coupling
+ I, R) B2 Q/ {自旋-自旋分裂:spin=spin splitting0 r; i5 s/ m! V% p: D5 F2 g
单峰:singlet,s: y3 Q3 e7 r5 i4 X6 ~# B
双峰:doublet,d- {3 a6 {7 l! ]9 b1 r! A+ p2 b
三重峰:triplet,t0 U7 b9 d+ H, z+ d/ z g; v" _
四重峰:quartet' [4 s4 y1 l1 M8 n5 P" N( n
五重峰:quintet
) z% e1 K* ~9 }' S! i$ h, z% L六重峰:sextet
' O; N# n. e- f. F偕偶:geminal coupling
' @4 W, @0 X' O5 U2 q% e邻偶:vicinal coupling
5 A2 m& B! g+ h4 V% {% P远程偶合:long range coupling
# ]2 I; O% \: b }- w, d+ i磁等价:magnetic eqivalence
4 h1 u9 d) Z. b' M自旋系统:spin system. [6 P5 v9 A+ x# b1 k) x
一级光谱:first order spectrum/ f) j5 D7 f B! i; b$ o- c/ A
二级光谱(二级图谱):second order spectrum
. R" m) J& G& j( U$ GC-H光谱:C-H correlated spectroscopy,C-H COSY8 [# I$ O$ Y( n3 t
第十七章 质谱法% j# n* y& |8 W% y
质谱分析法:mass spectrometry
3 G+ E" y& ^+ |6 Q质谱:mass spectrum,MS3 R/ a1 }- c' F* w" p
棒图:bar graph
/ H3 N9 |. k5 B% `1 R, B选择离子检测:selected ion monitoring ,SIM
6 U9 {0 R; t: G7 r$ n3 Q8 z直接进样:direct probe inlet ,DPI
6 s2 c) S2 \! o8 H接口:interface2 F/ k2 Z/ A. {9 Y
气相色谱-质谱联用:gas chromatography-mass spectrometry,GC-MS" b4 p. ^" Y: S) e. u% G+ ^
高效液相色谱-质谱联用:high performance liquid chromatography-mass spectrometry,HPLC-MS$ a9 A8 r* f- d0 c# l1 ~ l
电子轰击离子源:electron impact source,EI: l% v; p' M6 i/ E0 R2 C
离子峰:quasi-molecular ions ~$ e- x s" B( r, ?
化学离子源:chemical ionization source,CI( O; d8 U2 ^* p& Q& d
场电离:field ionization,FI+ [% C9 O1 @$ w
场解析:field desorptiion,FD
( @; ~, p( h& [+ f1 ?快速原子轰击离子源:fast stom bombardment ,FAB
/ r& b7 z5 o6 L. y, P9 t质量分析器:mass analyzer
- R* Y- V, _# l5 q. z+ B, a( v磁质谱仪:magnetic-sector mass spectrometer
, K$ K, T% j2 t7 f6 Q# E四极杆质谱仪(四极质谱仪):quadrupole mass spectrometer* k& d8 t* I" s' x, \0 ], G- b
原子质量单位:amu
0 d7 u9 ?: }3 i' d' ~离子丰度:ion abundance
: O- c# X! }# o! i3 O+ Z7 _相对丰度(相对强度):relative avundance
% r: W+ v) Z) K7 F基峰:base peak; |* i, p+ `+ C, f0 Q
质量范围:mass range7 p# U. Y: p- O1 Y) ?/ m! s7 B" i) ]
分辨率:resolution
2 N+ v& X) M. E: ~/ S% m3 c0 \灵敏度:sensitivity9 ]' L( Z7 i3 e
信噪比:S/N
0 \) I- B$ T K! A7 j& U$ B分子离子:molecular ion% U9 q5 D( a* D6 R2 @
碎片离子:fragment ion0 c9 F: C* f1 J7 b8 f `4 q% e
同位素离子:isotopic ion3 `$ S c2 V# k
亚稳离子:metastable ion
; ?5 V/ o/ W6 t: {+ R亚稳峰:metastable peak8 {+ P% R2 \& }5 Y
母离子:paren ion
# S- U' K4 B( x: B) K( q子离子:daughter
2 V( ~ n4 f9 V) q! n8 y含奇数个电子的离子:odd electron
; G0 j. U# \/ y- g0 x' ]& P: G: G含偶数个电子的离子:even eletron,EE" N1 r; o3 o f. C# V2 F& |& m
均裂:homolytic cleavage
7 Z9 c8 }0 m! N5 p/ G, a4 e异裂(非均裂):heterolytic cleavage
4 L- Z" A& ], y, T' x1 k半均裂:hemi-homolysis cleavage
' G# y4 X! x, z4 X重排:rearragement
' T' z9 `/ z" r4 U! U分子量:MW
* k8 u0 j& B Iα-裂解:α-cleavage7 r- h4 P% y0 H* q
第十八章 色谱分析法概论+ \3 Z$ q5 ~$ i" O. C! q
色谱法(层析法):chromatography
/ g/ h' t' `7 e5 E7 `固定相:stationary phase9 m! \5 ~4 [9 h W/ b9 p; a
流动相:mobile phase
, B/ ?. Q' S* D# Y超临界流体色谱法:SFC" p |( W. q+ f* r; o a2 h
高效毛细管电泳法:high performance capillary electroporesis,HPEC9 W: l4 ~7 a7 e$ k% T
气相色谱法:gas chromatography,GC! C" J% `! r7 X3 d$ c% E
液相色谱法:liquid cromatography,LC
5 l' U# p+ t* N" Y3 l超临界流体色谱法:supercritical fluid chromatography,SFC5 |. }2 u' U& @8 A" L
气-固色谱法:GSC
& F4 X+ G* Q/ I8 d& M* ^* l% y( F气-液色谱法:GLC
: t+ Z z5 q+ w" [* j4 U液-固色谱法:LSC+ @$ e; y0 y" P/ G
液-液色谱法:LLC
, Q. a# e- G/ s: U. |- u柱色谱法:column chromatography
& ^# e Q( b& j& g R填充柱:packed column
# z3 W( H, E/ `毛细管柱:capillary column3 {/ z6 h: y' y: F9 m
微填充柱:icrobore packed column
6 M& n# m& m" c4 N( z4 J高效液相色谱法:high performance liquid chromatography,HPLC
* g! n) S2 g2 H: `& K% f平板色谱法:planar
2 R: @7 O' Q& _) t平板色谱法:plane chromatography" Z) @6 J ?8 ]
纸色谱法:paper chromatography
( m7 i$ ^# l& d8 f+ l" O4 E0 f4 W! q9 ^; n薄层色谱法:thin layer chromatography,TLC
, t6 p- z" Y ~( q- l( P$ k' M8 ~薄膜色谱法;thiin film chomatography
+ `1 N7 I8 R# k+ ~/ `# s* Q. s毛细管电泳法:capillary electrophoresis,CE% T% M. r$ n: v8 W7 y H5 Z
分配色谱法:partition chromatography+ x B5 h+ [( @, E9 Q! |
吸附色谱法:adsorpion chromaography0 W u: @' C4 W i
离子交换色谱法:ion exchange chromatography,IEC" _: V$ l+ z5 M+ D$ C- P5 L' g
空间排阻色谱法:steric exclusion chromatography,SEC
& B, v* W' P3 Y4 x2 ` `亲和色谱法:affinity chromatography
& N8 A# U0 D! H7 C0 u" E- W7 Q! V分配系数:distribution cofficient. \( k* l @$ f1 Z! `4 {& j8 _
狭义分配系数:partition coefficient
1 P3 E& j0 ]( J/ v- s7 B# o1 Q9 K凝胶色谱法:gel chromatography
% R) }- y f! X1 p凝胶渗透色谱法:gel permeation chromatography,GPC' A$ r4 f( ]3 V/ J9 k* J6 k. m
凝胶过滤色谱法:gel filtration chromatography,GFC- R( ?$ V6 L z4 w/ _
渗透系数:permeation coefficien;Kp: u6 a& O! G' G5 `7 o2 u0 v4 t
化学键合相色谱法:chemically bonded-phase chromatography
1 L3 c0 U# f: `. D# m6 `) M' h5 V分配系数:distribution coefficient
" m; a. K6 B) s. I4 f) @靛菁绿:indocyanine' \& t- C% \( _" j- o# p
气相色谱-傅立叶变换红外光谱:GC-FTIR
" b, A6 ^, w" f: R; O/ H6 G第十九章 经典液相色谱法 ~2 h5 f" U! D' w3 Z# ^
薄层色谱法:TLC
% S# H W3 l* `9 e0 W吸附:adsorption# S& l, _0 A5 L( H+ ]; s
活化:activation
3 A/ L: u; o' e0 }脱活性:deactivation" A" Q8 f! k u @- ?; c% o
交联度:degree of cross linking& F8 q p7 G1 l) D) s8 T
交换容量:exchange capacity$ E, E' W9 C0 `6 b& z9 g
薄层板:thin layer plate1 G" { _( p5 ?1 F0 \, _3 w
展开剂:developing solvent ,developer& D6 Z. [5 W9 O6 m3 |* T7 T
临界胶束浓度:criticak micolle concentration ,CMC9 T6 Z! H' Y) k
相对比移值:relative Rf, Rr6 d8 z5 _7 l" }2 m& x5 G* N
分离度:resolution ,R1 b# `( Y) u8 P6 g4 k
分离数:separation number,SN6 T, }, e7 }" n" s& X; s
煅石膏:Gypsum4 j1 J# g9 P3 R4 \9 @, s# v
羧甲基纤维素钠:CMC-Na
1 P5 N) t S1 _( ^: F吸收光谱联用:TLC-UV
. m& f' Z- Q" |1 o薄层色谱-荧光联用:TLC-F
4 p- R) Q" R( `+ i( L6 G薄层色谱-红外吸收光谱联用:TLC-IR
) P% S/ G/ k2 M- E9 I薄层色谱法:TLC-MS
& a2 s5 }: l1 K u% P* [纸色谱法:paper chromatography- t; ^) o- M7 n7 z5 r
上行展开:ascending development
6 v( M: I1 X' h# p. R下行法展开:descending development
z0 O1 H4 C& M双向展开:two dimensional develoooment% J8 v W8 c2 K# g
* Q4 `+ q0 s. W7 v6 H+ [
+ I5 }( b5 W5 B; n2 T9 w Z(节选) |
-
1
评分人数
-
|